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Review Articles

Vol. 13 No. sp9 (2026): Recent Advances in Agriculture

Applications and future potential of nano clay polymer composites in agriculture

DOI
https://doi.org/10.14719/pst.16847
Submitted
18 July 2026
Published
31-10-2026

Abstract

Nanotechnology is showing promise as a revolutionary strategy to improve crop productivity, environmental sustainability and resource efficiency. Nano clay polymer composites (NCPCs) have drawn considerable interest among advanced nanomaterials because of their distinct physicochemical characteristics and broad agricultural applications. Montmorillonite, Bentonite and Hectorite are examples of nano clays, which are layered silicate minerals with large surface area, nanoscale dimensions and potent adsorption capabilities. They form hybrid materials with enhanced mechanical strength, thermal stability and barrier properties when integrated into polymer matrices. Water, nutrients and agrochemicals flow through a convoluted diffusion pathway created by the layered structure of nano clays, allowing for regulated and prolonged release. The NCPCs can have phase-separated, intercalated, or exfoliated structures depending on how they are dispersed within the polymer matrix; exfoliated forms function better. In agricultural applications, NCPCs function as soil conditioners, smart fertiliser carriers and plant protection delivery systems. They improve soil aggregation, enhance water retention and increase nutrient availability, particularly in coarse-textured soils. Nano-enabled fertilisers facilitate synchronised nutrient release, improving nutrient use efficiency while minimising leaching and volatilisation losses. Emerging applications include delivery of nucleic acids for plant disease management, antimicrobial crop protection and micronutrient nanocomplexes that enhance bioavailability and soil biological activity. Overall, NCPCs offer a promising pathway toward sustainable and precision agriculture, Future research should focus on developing biodegradable polymer systems, optimising scalable synthesis methods, conducting long term field evaluations and estabilishing regulatory frameworks to enable their safe and agricultural application.

References

  1. 1. Lee SM, Tiwari D. Organo and inorgano-organo-modified clays in the remediation of aqueous solutions: an overview. Appl Clay Sci. 2012;59:84–102. https://doi.org/10.1016/j.clay.2012.02.006
  2. 2. Sinha A, Narang H, Bhattacharya S. Mechanical properties of natural fibre polymer composites. J Polym Eng. 2017;37. https://doi.org/10.1515/polyeng-2016-0362
  3. 3. Reduwan Billah SM. Composites and nanocomposites. In: Jafar Mazumder MA, Sheardown H, Al-Ahmed A, editors. Functional polymers. Cham: Springer International Publishing; 2019. p. 1–67.
  4. 4. Savic Gajic I, Stojiljkovic S, Savic I, Gajic D. Industrial application of clays and clay minerals. 2014. p. 379–402.
  5. 5. Xing H, Liu X, He Q, Wang W. Progress and prospects of polymer/one-dimensional nanoclay superabsorbent composites. Polymers. 2025;17(5):669. https://doi.org/10.3390/polym17050669
  6. 6. Awasthi A, Jadhao P, Kumari K. Clay nano-adsorbent: structures, applications and mechanism for water treatment. SN Appl Sci. 2019;1(9):1076. https://doi.org/10.1007/s42452-019-0858-9
  7. 7. Lau KT, Gu C, Hui D. A critical review on nanotube and nanotube/nanoclay related polymer composite materials. Compos Part B Eng. 2006;37(6):425–36. https://doi.org/10.1016/j.compositesb.2006.02.020
  8. 8. Arya A, Sharma A. Investigation on enhancement of electrical, dielectric and ion transport properties of nanoclay-based blend polymer nanocomposites. Polym Bull. 2020;77. https://doi.org/10.1007/s00289-019-02893-x
  9. 9. Wilson J. Handbook of clay science, F. Bergaya, B.K.G. Theng, G. Lagaly, Elsevier, Amsterdam (2006), 1224 pp., £105, ISBN: 978-0-08-044183-2. Geoderma. 2007;139:420–1. https://doi.org/10.1016/j.geoderma.2007.02.001
  10. 10. Pacal I, Kunduracioğlu I, Alma M, Deveci M, Kadry S, Nedoma J, et al. A systematic review of deep learning techniques for plant diseases. Artif Intell Rev. 2024;57. https://doi.org/10.1007/s10462-024-10944-7
  11. 11. Kausar A, Ahmad I, Aldaghri O, Ibnaouf KH, Eisa MH. Nanoclay-reinforced nanocomposite nanofibers-fundamentals and state-of-the-art developments. Minerals. 2023;13(6):817. https://doi.org/10.3390/min13060817
  12. 12. Abulyazied D, Ene A. An investigative study on the progress of nanoclay-reinforced polymers: preparation, properties and applications: a review. Polymers. 2021;13:4401. https://doi.org/10.3390/polym13244401
  13. 13. Pavón E, Martín-Rodríguez R, Perdigón AC, Alba MD. New trends in nanoclay-modified sensors. Inorganics. 2021;9(6):43. https://doi.org/10.3390/inorganics9060043
  14. 14. Uddin MN, Hossain M, Mahmud N, Alam S, Hossain M, Mahedi S, et al. Research and applications of nanoclays: a review. SPE Polym. 2024;5:507–35. https://doi.org/10.1002/pls2.10146
  15. 15. Beyer G. Nanocomposites: a new class of flame retardants for polymers. Plast Addit Compd. 2002;4(10):22–8. https://doi.org/10.1016/S1464-391X(02)80151-9
  16. 16. Maiti M, Sadhu S, Bhowmick AK. Ethylene-octene copolymer (Engage)-clay nanocomposites: preparation and characterization. J Appl Polym Sci. 2006;101(1):603–10. https://doi.org/10.1002/app.23348
  17. 17. Mohapi M, Sefadi JS, Mochane MJ, Magagula SI, Lebelo K. Effect of LDHs and other clays on polymer composite in adsorptive removal of contaminants: a review. Crystals. 2020;10(11):957. https://doi.org/10.3390/cryst10110957
  18. 18. Quigley J, Baird D. Improved mechanical properties of organoclay/nylon 6 nanocomposites prepared via a supercritical carbon dioxide-aided, melt blending method. Polym Compos. 2014;36. https://doi.org/10.1002/pc.22969
  19. 19. Albdiry M, Yousif B, Ku H, Lau K. A critical review on the manufacturing processes in relation to the properties of nanoclay/polymer composites. J Compos Mater. 2013;47(9):1093–115. https://doi.org/10.1177/0021998312445592
  20. 20. Ge T, Kalathi JT, Halverson JD, Grest GS, Rubinstein M. Nanoparticle motion in entangled melts of linear and nonconcatenated ring polymers. Macromolecules. 2017;50(4):1749–54. https://doi.org/10.1021/acs.macromol.6b02632
  21. 21. Burmistr M, Sukhyi K, Shilov V, Pissis P, Spanoudaki A, Sukha I, et al. Synthesis, structure, thermal and mechanical properties of nanocomposites based on linear polymers and layered silicates modified by polymeric quaternary ammonium salts (ionenes). Polymer. 2005;46:12226–32. https://doi.org/10.1016/j.polymer.2005.10.094
  22. 22. Müller K, Bugnicourt E, Latorre M, Jorda M, Echegoyen Sanz Y, Lagaron JM, et al. Review on the processing and properties of polymer nanocomposites and nanocoatings and their applications in the packaging, automotive and solar energy fields. Nanomaterials. 2017;7(4):74. https://doi.org/10.3390/nano7040074
  23. 23. Salmi Z, Benzarti K, Chehimi MM. Diazonium cation-exchanged clay: an efficient, unfrequented route for making clay/polymer nanocomposites. Langmuir. 2013;29(44):13323–8. https://doi.org/10.1021/la402710r
  24. 24. Sharma S, Poddar MK, Moholkar VS. Enhancement of thermal and mechanical properties of poly(MMA-co-BA)/Cloisite 30B nanocomposites by ultrasound-assisted in-situ emulsion polymerization. Ultrason Sonochem. 2017;36:212–25. https://doi.org/10.1016/j.ultsonch.2016.11.029
  25. 25. Zakaria C, Boukoussa B, Zaoui A, Belbachir M, Meghabar R. Structural, morphological and thermal properties of nanocomposites poly(GMA)/clay prepared by ultrasound and in-situ polymerization. Ultrason Sonochem. 2018.
  26. 26. Gillela S, Yadav S, Kelkar BU, Sihag K, Dangtungee R, Bhuyar P, et al. Advancing thermoset polymer composites with nanoclay reinforcement: a comprehensive investigation within composite interfaces. Compos Interfaces. 2024;31:1–43. https://doi.org/10.1080/09276440.2024.2373486
  27. 27. Pavlidou S, Papaspyrides CD. A review on polymer-layered silicate nanocomposites. Prog Polym Sci. 2008;33(12):1119–98. https://doi.org/10.1016/j.progpolymsci.2008.07.008
  28. 28. Kausar A. A review of fundamental principles and applications of polymer nanocomposites filled with both nanoclay and nano-sized carbon allotropes-graphene and carbon nanotubes. J Plast Film Sheeting. 2020;36(2):209–28. https://doi.org/10.1177/8756087919884607
  29. 29. Kumar A, Zhang R, Venkatesan M, Stamenov P, Coey JMD. Exfoliation of hematite: morphological, structural and magnetic investigations. J Magn Magn Mater. 2022;542:168507. https://doi.org/10.1016/j.jmmm.2021.168507
  30. 30. Kamgar R, Salimi Naghani M, Heidarzadeh H, Nasiri Ardali F. Modeling nanoclay effects on different parameters of a clayey sand. Model Earth Syst Environ. 2021;7(2):795–808. https://doi.org/10.1007/s40808-020-00987-4
  31. 31. Aly M, Hashmi MSJ, Olabi AG, Messeiry M, Hussain AI. Effect of nano clay particles on mechanical, thermal and physical behaviours of waste-glass cement mortars. Mater Sci Eng A. 2011;528(27):7991–8. https://doi.org/10.1016/j.msea.2011.07.058
  32. 32. Mirgozar Langaroudi MA, Mohammadi Y. Effect of nano-clay on workability, mechanical and durability properties of self-consolidating concrete containing mineral admixtures. Constr Build Mater. 2018;191:619–34. https://doi.org/10.1016/j.conbuildmat.2018.10.044
  33. 33. Niu XJ, Li QB, Hu Y, Tan YS, Liu CF. Properties of cement-based materials incorporating nano-clay and calcined nano-clay: a review. Constr Build Mater. 2021;284:122820. https://doi.org/10.1016/j.conbuildmat.2021.122820
  34. 34. Ponce AG, Alvarez V. Nano-clays from natural and modified montmorillonite with and without added blueberry extract for active and intelligent food nanopackaging materials. Mater Chem Phys. 2017;194:283–92. https://doi.org/10.1016/j.matchemphys.2017.03.052
  35. 35. Liu M, Guo T. Preparation and swelling properties of crosslinked sodium polyacrylate. J Appl Polym Sci. 2001;82:1515–20. https://doi.org/10.1002/app.1990
  36. 36. Bathaei A, Streimikiene D. Renewable energy and sustainable agriculture: review of indicators. Sustainability. 2023;15. https://doi.org/10.3390/su151914307
  37. 37. Reynolds D, Elrich DE, Young EG, Amoozegar A, Booltink HWG, Bouma J. Methods of soil analysis, part 4: physical methods. Soil Sci Soc Am. 2002.
  38. 38. Verma M, De N, Pandey P. Characterization of water retention and release capacity of innovative nano clay polymer composite superabsorbent. 2017;42:42–8.
  39. 39. Ghasabkolaei N, Choobbasti AJ, Roshan N, Ghasemi SE. Geotechnical properties of the soils modified with nanomaterials: a comprehensive review. Arch Civ Mech Eng. 2017;17(3):639–50. https://doi.org/10.1016/j.acme.2017.01.010
  40. 40. Majid MSA, Ridzuan MJM, Lim KH. Effect of nanoclay filler on mechanical and morphological properties of Napier/epoxy composites. In: Goh KL, M.K. A, De Silva RT, Thomas S, editors. Interfaces in particle and fibre reinforced composites. Woodhead Publishing; 2020. p. 137–62. https://doi.org/10.1016/B978-0-08-102665-6.00006-6
  41. 41. Harilal S, Harikumar P, Narayanan RU, K R G, Dileep A, Vijayanand V, et al. The role of nanoclays on the properties and performance of soil and construction materials: a comprehensive review. 2024. p. 127–50. https://doi.org/10.1016/B978-0-443-13390-9.00008-4
  42. 42. Shlapa Y, Solopan S, Sarnatskaya V, Siposova K, Garcarova I, Veltruska K, et al. Cerium dioxide nanoparticles synthesized via precipitation at constant pH: synthesis, physical-chemical and antioxidant properties. Colloids Surf B Biointerfaces. 2022;220:112960. https://doi.org/10.1016/j.colsurfb.2022.112960
  43. 43. Shams Maleki Y, Sharafi H. The exploration into the effect of nanoclay additive on soil geotechnical-engineering basic properties. Adv Environ Biol. 2014;8:989–92.
  44. 44. Karkush M, Almurshedi A, Karim H. Investigation of the impacts of nano-clay on the collapse potential and geotechnical properties of gypseous soils. 2020.
  45. 45. Zhao L, Zhou X, Kang Z, Peralta-Videa JR, Zhu YG. Nano-enabled seed treatment: a new and sustainable approach to engineering climate-resilient crops. Sci Total Environ. 2024;910:168640. https://doi.org/10.1016/j.scitotenv.2023.168640
  46. 46. Singh S, Pathak S, Yogita, Singh J, Kamboj M, Singh V. Nano-seed coating technologies for enhancing vegetable seed performance and stress tolerance. J Agric Ecol Res Int. 2024;25:278–95. https://doi.org/10.9734/jaeri/2024/v25i6658
  47. 47. Neme K, Nafady A, Uddin S, Tola YB. Application of nanotechnology in agriculture, postharvest loss reduction and food processing: food security implication and challenges. Heliyon. 2021;7(12). https://doi.org/10.1016/j.heliyon.2021.e08539
  48. 48. Padidar M, Jalalian A, Asgari K, Abdouss M, Najafi P, Honarjoo N, et al. The impacts of nanoclay on sandy soil stability and atmospheric dust control. 2016;81:193–6.
  49. 49. Abd-Elsalam KA, Mehmood MA, Ashfaq M, Abdelkhalek TE, Hassan RK, Ravichandran M. Liquid nanoclay: synthesis and applications to transform an arid desert into fertile land. Soil Syst. 2024;8(3):73. https://doi.org/10.3390/soilsystems8030073
  50. 50. Adhikary S, Mandal N, Rakshit R, Das A, Kumar V, Kumari N, et al. Field evaluation of zincated nanoclay polymer composite (ZNCPC): impact on DTPA-extractable Zn, sequential Zn fractions and apparent Zn recovery under rice rhizosphere. Soil Tillage Res. 2020;201:104607. https://doi.org/10.1016/j.still.2020.104607
  51. 51. Torney F, Trewyn B, Lin V, Wang K. Mesoporous silica nanoparticles deliver DNA and chemicals into plants. Nat Nanotechnol. 2007;2:295–300. https://doi.org/10.1038/nnano.2007.108
  52. 52. Blachnio M, Kusmierek K, Swiatkowski A, Derylo-Marczewska A. Adsorption of phenoxyacetic herbicides from water on carbonaceous and non-carbonaceous adsorbents. Molecules. 2023;28(14):5404. https://doi.org/10.3390/molecules28145404
  53. 53. Worrall E, Bravo-Cazar A, Nilon A, Fletcher S, Robinson K, Carr J, et al. Exogenous application of RNAi-inducing double-stranded RNA inhibits aphid-mediated transmission of a plant virus. Front Plant Sci. 2019;10. https://doi.org/10.3389/fpls.2019.00265
  54. 54. Sánchez-López E, Gomes D, Esteruelas G, Bonilla L, Lopez-Machado AL, Galindo R, et al. Metal-based nanoparticles as antimicrobial agents: an overview. Nanomaterials. 2020;10(2):292. https://doi.org/10.3390/nano10020292
  55. 55. Brandelli A. Nanocomposites and their application in antimicrobial packaging. Front Chem. 2024;12. https://doi.org/10.3389/fchem.2024.1356304
  56. 56. Brandelli A. Toxicity and safety evaluation of nanoclays. 2018. p. 57–76. https://doi.org/10.1007/978-3-030-05144-0_4
  57. 57. Nakache E, Poulain N, Candau F, Orecchioni A, Irache J. Biopolymer and polymer nanoparticles and their biomedical applications. In: Handbook of nanostructured materials and nanotechnology. 2000. p. 577–635. https://doi.org/10.1016/B978-012513760-7/50063-0
  58. 58. Tarafdar J, Subramaniam KS. Prospects of nanotechnology in Indian farming. Indian J Agric Sci. 2011;81:887–93.
  59. 59. Noellsch AJ, Motavalli PP, Nelson KA, Kitchen NR. Corn response to conventional and slow-release nitrogen fertilizers across a claypan landscape. Agron J. 2009;101(3):607–14. https://doi.org/10.2134/agronj2008.0067x
  60. 60. Rakshitha K, Chobhe K, Dandapani R, Sahoo R, Kumar A, Saini R, et al. Effect of nitrogen fertilizers applied through nano clay polymer composites on nitrogen use efficiency of rice. Int J Plant Soil Sci. 2023;35:1252–9. https://doi.org/10.9734/ijpss/2023/v35i203924
  61. 61. Biswas D. Synthesis and characterization of nanoclay-polymer composites from soil clay with respect to their water-holding capacities and nutrient-release behavior. J Appl Polym Sci. 2013.
  62. 62. Hussein MZ bin, Yahaya AH, Zainal Z, Kian LH. Nanocomposite-based controlled release formulation of an herbicide, 2,4-dichlorophenoxyacetate encapsulated in zinc-aluminium-layered double hydroxide. Sci Technol Adv Mater. 2005;6:956–62. https://doi.org/10.1016/j.stam.2005.09.004
  63. 63. Ditta A. Role of nanoclay polymers in agriculture: applications and perspectives. 2019. p. 323–34. https://doi.org/10.1201/9781351256841-14
  64. 64. Grillo R, Abhilash P, Fraceto L. Nanotechnology applied to bio-encapsulation of pesticides. J Nanosci Nanotechnol. 2016;16:1231–4. https://doi.org/10.1166/jnn.2016.12332
  65. 65. Jerobin J, Sureshkumar RS, Anjali CH, Mukherjee A, Chandrasekaran N. Biodegradable polymer based encapsulation of neem oil nanoemulsion for control release of AZA-A. Carbohydr Polym. 2012;90:1750–6. https://doi.org/10.1016/j.carbpol.2012.07.064
  66. 66. OH JW, Chun SC, Chandrasekaran M. Preparation and in vitro characterization of chitosan nanoparticles and their broad-spectrum antifungal action compared to antibacterial activities against phytopathogens of tomato. Agronomy. 2019;9(1):21. https://doi.org/10.3390/agronomy9010021
  67. 67. Mosquera J, García I, Liz-Marzán LM. Cellular uptake of nanoparticles versus small molecules: a matter of size. Acc Chem Res. 2018;51(9):2305–13. https://doi.org/10.1021/acs.accounts.8b00292
  68. 68. Padil VVT, Akshay Kumar KP, Murugesan S, Torres-Mendieta R, Wacławek S, Cheong JY, et al. Sustainable and safer nanoclay composites for multifaceted applications. Green Chem. 2022;24(8):3081–114. https://doi.org/10.1039/D1GC03949K
  69. 69. Rao, Pochan JM. Mechanics of polymer−clay nanocomposites. Macromolecules. 2007;40(2):290–6. https://doi.org/10.1021/ma061445w
  70. 70. Su Y, Zhou X, Meng H, Xia T, Liu H, Rolshausen P, et al. Cost-benefit analysis of nanofertilizers and nanopesticides emphasizes the need to improve the efficiency of nanoformulations for widescale adoption. Nat Food. 2022;3. https://doi.org/10.1038/s43016-022-00647-z
  71. 71. Jk N, Subramanian S. Polymer composites for sustainable nutrient recovery and agriculture: functional modifications and economic benefits. Water Sci Technol. 2025;93:80–111. https://doi.org/10.2166/wst.2025.183
  72. 72. Sharma N. Future perspectives of clay based nanocomposites as sustainable materials. J Adv Res Altern Energy Environ Ecol. 2026;13:177–87. https://doi.org/10.24321/2455.3093.202603

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