Synthesis and characterization of groundnut shell carbon nanosheets for treating greywater: A step towards a circular economy

P P Chidambaram; K Ramalingam; S S Rakesh; K Raja; P T Ramesh; C Prabakaran; M Teja

doi:10.14719/pst.5499

Authors

P P Chidambaram Centre for Water and Geospatial Studies, Tamil Nadu Agricultural University, Coimbatore 641 003, Tamil Nadu, India https://orcid.org/0000-0002-7237-9481
K Ramalingam Department of Remote Sensing and GIS, Tamil Nadu Agricultural University, Coimbatore 641 003, Tamil Nadu, India https://orcid.org/0000-0001-6659-9587
S S Rakesh Department of Environmental Sciences, Tamil Nadu Agricultural University, Coimbatore 641 003, Tamil Nadu, India https://orcid.org/0000-0001-8896-2279
K Raja Centre for Nano Science and Technology, Tamil Nadu Agricultural University, Coimbatore 641 003, Tamil Nadu, India https://orcid.org/0000-0003-2750-8085
P T Ramesh Department of Environmental Sciences, Tamil Nadu Agricultural University, Coimbatore 641 003, Tamil Nadu, India https://orcid.org/0000-0003-1157-650X
C Prabakaran Department of Environmental Sciences, Tamil Nadu Agricultural University, Coimbatore 641 003, Tamil Nadu, India https://orcid.org/0000-0003-2508-6544
M Teja Department of Environmental Sciences, Tamil Nadu Agricultural University, Coimbatore 641 003, Tamil Nadu, India https://orcid.org/0009-0007-1517-1856

DOI:

https://doi.org/10.14719/pst.5499

Keywords:

carbon nanosheet, groundnut shell, KOH, sewage wastewater treatment

Abstract

Carbon nanostructured materials, such as nanosheets, can be synthetically produced from various natural waste sources through carbonization and activation. Potassium hydroxide (KOH) is a well-known agent for creating porous structures and refining the micro or nanostructure of carbon. This study explores the effect of KOH, in both its solute and solid forms, on the production of carbon from groundnut shells. Using KOH activation and thermal treatment, carbon nanosheets were synthesized from groundnut shells. The surface microstructure and individual carbon nanosheets showed significant changes when treated with solute KOH compared to solid KOH. This highlights that treatment with solute KOH is an efficient and cost-effective method for carbon nanosheet production. A column study revealed that using groundnut shell carbon nanosheets (GSCNS) to treat sewage wastewater resulted in a reduction in BOD from 393 mg L-1 to 112.23 mg L-1 (71.5%) and COD from 512.70 mg L-1 to 125 mg L-1 (75.6%). Additionally, GSCN treatment led to a 40-60% reduction in the cations and anions in sewage wastewater. This study emphasizes the effective utilization of groundnut shell-derived carbon nanosheets as an eco-friendly and cost-effective solution for wastewater treatment, addressing the environmental challenges of untreated sewage discharge in underdeveloped and developing regions.

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